Chemically-induced redox switching of a metalloprotein reveals thermodynamic and kinetic heterogeneity, one molecule at a time.
نویسندگان
چکیده
Oxidation (off state) and reduction (on state) of a single azurin molecule is monitored, one electron at a time, which depend on the chemical redox potential. By analysing the fluorescence time traces from individual azurin molecules, reaction kinetics and redox thermodynamics were determined.
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ورودعنوان ژورنال:
- Chemical communications
دوره 50 93 شماره
صفحات -
تاریخ انتشار 2014