Chemically-induced redox switching of a metalloprotein reveals thermodynamic and kinetic heterogeneity, one molecule at a time.

نویسندگان

  • Namik Akkilic
  • Fenna van der Grient
  • Muhammad Kamran
  • Nusrat J M Sanghamitra
چکیده

Oxidation (off state) and reduction (on state) of a single azurin molecule is monitored, one electron at a time, which depend on the chemical redox potential. By analysing the fluorescence time traces from individual azurin molecules, reaction kinetics and redox thermodynamics were determined.

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عنوان ژورنال:
  • Chemical communications

دوره 50 93  شماره 

صفحات  -

تاریخ انتشار 2014